Abstract
In the past, the repair of deteriorated pipework involved the welding of plates and sleeves, the use of bespoke clamps or the partial replacement of the faulty section. In recent years, however, the use of polymeric composite materials for the repair of pipes has gained worldwide support and interest. The main reasons for this are: the composite repair can be based on engineered structural calculations in accordance with internationally recognised standards; unlike welding, it is a safe cold process that can be carried out in areas where hot work is prohibited; it can be carried out at lower cost and provide long repair life sufficient to be taken as a permanent repair.
Pipelines, especially those of large diameter, can efficiently transport large volumes of liquids and gases over long distances. Operating over long distances through various landscapes, environments and conditions, pipelines can be subject to internal and external effects from numerous factors. Differences in height cause internal pressure fluctuations, while changes in temperature cause the pipe material to expand and contract; from these behaviours, pipelines are subjected to physical loads such as bending, shear, torsion and fatigue. At the same time, the inner walls of the pipes can be exposed to corrosion and chemical attack, depending on the chemicals involved in the media. Similarly, under conditions of inadequate protection, pipes are also subject to external corrosion.
These effects, acting alone or in combination, can cause damage to the pipe wall in the form of metal loss and eventually lead to through-wall defects, leading to leakage problems. Leaks can also have disastrous consequences, meaning shutdowns and environmental impact. For this reason, it is incumbent on facility owners and operators to take proactive precautions to prevent the worst from happening.
Belzona SuperWrap II composite repair
Belzona SuperWrap II is a pipe repair technology based on a polymer-based composite of epoxy resin and reinforcing fibres, using a wet-wrapping technique in which the resin-impregnated reinforcing fibres are wrapped directly around the pipe defectand cured.
Two material properties are key to the development of composite materials for the repair of wall thinning and leakage defects in pipes: mechanical strength and stiffness. Mechanical strength depends on the maximum tensile stress that a material can withstand without failure and is determined from its tensile strength. Stiffness, on the other hand, refers to the elasticdeformation of a material when a force is applied and is defined by the Young's modulus (also known as tensile modulus or modulus of elasticity). In the case of polymeric composites, the mechanical strength and stiffness depend to a large extent on the properties of the reinforcing fibre. The resin is responsible for transferring the load between the reinforcing fibres. The success of a composite repair also depends on the adhesive strength of the resin, as it must be integrated with the pipe substrate.
In the development of the Belzona SuperWrap II, several combinations of resins and reinforcing fibres were considered. In the end, a two-component epoxy resin with 100% solids content, consisting of a phenolic novolac base (main agent) and an amine solidifier, was chosen. The main reason for this was the emphasis on the fact that epoxy resins can achieve better adhesion and mechanical strength compared to other functional polymer groups, including polyurethanes, methacrylates, alkyds, vinyls and polyesters. The possibility of forming highly cross-linked polymer matrices, which are the basis for excellent heat and chemical resistance, should also be supplemented as one of the reasons for concluding that phenolic novolac epoxy resins are the best choice.
In general, epoxy resins are slow to cure at low temperatures, but when heat is applied, the reaction is activated and the resin cures in a shorter time. Taking into account the temperature conditions at the time of application, which tend to be affected by climatic differences, two types of resin were initially developed (Belzona 1981 and Belzona 1982 resins), followed by Belzona 1983 resin with improved heat resistance (see Table 1).Today, three different types of resin are available, allowing the user to select the most suitable material depending on the temperature conditions.
Table 1 – Usable temperature ranges for each resin
The most suitable reinforcing fibre material was selected on the basis of the material's mechanical strength and stiffness, as well as its workability (cutting, resin impregnation, on-site handling, etc.). After carefully considering all the pros and cons of each material, it was decided to use a hybrid fibre, a combination of carbon fibre and glass fibre, which is produced as Belzona 9381 to be an optimised reinforcement fibre sheet for Belzona SuperWrap II. Belzona 9381 reinforcing sheet has a two-layer construction, with carbon fibre on the front and glass fibre on the back, to maximise the benefits of both fibres and to achieve the most efficient distribution and arrangement in terms of physical properties and workability. This is because the glass fibre and epoxy resin layer are designed to act as an insulator to prevent corrosion currents from flowing through the conductive carbon fibre. The reinforcing fibre sheets are available in severaldifferent widths to accommodate different pipe diameters, with wider sheets being particularly useful for special geometries such as bends, tees, flanges, reducers, as well as the walls and roofs of large storage tanks.
After the resin-impregnated reinforcing fibres have been wrapped around the pipe, a special consolidating film called Belzona 9382 is used to hold the repair in place until the resin has cured. Once the resin has cured, the film can be easily removed.
Image 2: Damaged pipeline after suffering from Corrosion Under Insulation (CUI)
Image 3:After rebuilding the pipe to original profile using Belzona 1111, several wraps of Belzona 9381 were applied
Image 4:The pipe repair before the removal of the release film
Compliance with standards
The Composite repair of pipework requires a high degree of reliability, especially in the case of high pressure piping systemsor for pipes carrying hazardous media. For this reason, rigorous third-party and in-house testing is carried out to demonstrate compliance with a series of requirements set out in ISO 24817 and ASME PCC-2. For the tests aimed at assessing the mechanical properties of the materials, plate specimens made of reinforcing fibre and each resin were used. On the other hand, in the pressure resistance test aimed at evaluating durability of the system, a short pipe spool with pseudo-defects of the specified dimensions was repaired with the system, followed by a pressure resistance test for confirmation. A summary of each test is given in Table 2.
Test results and verification
Table 3 shows some results of the physical property tests. In parentheses are the curing temperatures of the specimens.
In the tensile shear bond strength test, the bond strength of the resins is measured in two ways as: 1) cured for 7 days at specified temperature conditions (short-term condition), and 2) immersion in water for 1000 hours at specified temperature conditions (long-term condition), both using carbon steel as the adherend. The comparison of the results of the low and high temperature tests is intended to see the effect of temperature changes on the adhesive strength of the resins. All the results comply with the requirements of ISO 24817 in two respects:
(a) The tensile shear bond strength of each resin is >5 MPa for short- and long-term conditions
(b) For each resin, the long-term values are at least 30% of the short-term values
The glass transition temperature (Tg) is the temperature at which a polymer material begins to soften as it is heated. It is a common phenomenon for thermoplastics and its value is often referred to in assessing the thermal properties and thermal resistance of resin-based repair techniques. When the resin is heated while it is curing, the density of the cross-linking increases and the glass transition temperature rises. When Belzona 1981 resin is cured at 60°C, Belzona 1982 resin at 80°C and Belzona 1983 resin at 150°C, the glass transition temperatures are 90°C, 115°C and 188°C respectively (see Table 3).
Piping systems under pressure are subject to the Poisson effect. Due to the circumferential stresses occurring inside the pipe, the diameter of the pipe increases slightly, but at the same time there is a contraction in the axial direction and the pipe becomes shorter. Therefore, a Poisson's ratio close to the value of the pipe is required for the composites to be a suitable material to restore the mechanical strength of the pipelines. The Poisson's ratio of the Belzona SuperWrap II material is close enough to that of steel. This means that when a typical steel pipe is subjected to compressive or tensile loads, the accompanying SuperWrap II repair reacts similarly to the base metal.
mage 5: Belzona SuperWrap II being applied
Young's modulus (tensile modulus) is a measure of the stiffness of a material, and the SuperWrap II materials have high Young's modulus of 37-39 GPa, meaning that the repair will have good stiffness and bending moment. From a practical point of view, when assessing the performance of a composite pipe repair, it is reported that a standard modulus of elasticity of 6,895 MPa or higher is desirable,3 and the values of SuperWrap II materials arewell above this. On the other hand, considering that the Young's modulus of ordinary steel is about 200 GPa, SuperWrap II materials, which have about one-fifth, are far more elastic than steel, and in this sense, it can be said that SuperWrap II repairhas excellent elasticity and can easily follow the movement of the base metal.
The thermal expansion coefficient of a solid material indicates the extent to which its length and volume change when subjected to a change in temperature under constant pressure conditions. Piping, which is subjected to a variety of operating conditions, generally undergoes repeated expansion and contraction as a result of temperature changes. Therefore, composite materials used to restore the mechanical strength of pipe materials must also be able to cope with thermal strain. The linear expansion coefficient of Belzona SuperWrap II materialscured at ambient temperature are between 9.40 and 11.26 x 10-6 /K, which is close to that of ordinary steel (11-12.5 x 10-6 /K).4This means that the stress effect (thermal strain) on the adhered surface caused by the difference in thermal expansion between the composite materials and the base metal is minimal.
Table 4 shows the conditions for durability testing of the SuperWrap II composite materials.
The short-term pressure test evaluates the performance of Belzona SuperWrap II against wall thinning defects (no penetration). The objective is to determine the maximum level of wall thinning that can be repaired. The test is carried out on a short carbon steel spool with a pseudo-defect (wall loss) of a specified size. The repair is designed to restore the yield strength of the original pipe wall. The test pressure was calculated as the yield pressure of the test spool in its original sound condition(test pressures indicated in Table 4). The difference in test pressure between the Belzona 1981/1982 resins and Belzona 1983 resin is due to the different test spools used. All the resins passed the test and the results demonstrate that the repair conforms to the design specification and is able to restore the durability of the pipe material.
The long-term pressure test also evaluates the performance of Belzona SuperWrap II against thin-wall defects. Here, the durability of the repair is assessed after 1,000 hours of sustained loading by maintaining the pipe internal pressure at a constant level (test pressures indicated in Table 4). As a result, no cracks, delamination or any other degradation was observed and the test was therefore deemed a pass.
Image 6: A Belzona SuperWrap II application before being overcoated with Belzona 5811 (ImmersionGrade) for extra protection
Requirements for Belzona SuperWrap II application
The repair design of Belzona SuperWrap II is determined by strength calculations based on actual defective conditions of pipes in accordance with the ISO/ASME standards, which also take into account factors such as surface preparation method, pipe geometry, environmental conditions, operational/design pressures, etc. The repair is then carried out following the design, but there are certain conditions that must be adhered to during the application.
Firstly, to ensure the quality of the work, all Belzona SuperWrapII installers are required to attend and pass a validated training course. The course includes a practical test (as well as a theory exam), in which participants are asked to repair a pipe spool with a simulated defect, which must then pass a certain pressuretest.
As a strict rule, a compliant repair must always be conducted by trained installers. The ISO/ASME standards defines repair classes from class 1 to class 3. Class 1 is for low specification duties with least critical conditions such as pressure of <2 MPa and temperature of <40°C and since this is for systems that do not relate directly to personnel safety the repair jobs can be handled by installers alone. Class 2 and 3 however involve more critical scenarios, for example higher pressure and temperature conditions as well as systems transporting hazardous fluids; in those cases therefore the work must be supervised by a certified supervisor who has completed a higher level of training.Periodic annual renewal of qualifications is also compulsory for the installers and supervisors to ensure that they maintain and improve their skills after certification.
All the inspection results, including environmental measurements, surface roughness achieved by surface preparation conducted, batch numbers of products used, and resulting repair thickness, are recorded in QA/QC documents of each project. And this will be collected on all projects, including information on who was the installer/supervisor involved.
After use in service, Belzona SuperWrap II repairs can be revalidated or decommissioned upon reaching its design lifetime, depending on the decision made by the asset owner.
Belzona SuperWrap II repair solution is available worldwide through the network of Belzona International Distributors, and the applications can be carried out by trained and validatedpersonnel from third parties as long as they fulfil the prerequisites. By allowing the asset owner to choose who would carry out the design and also who would apply the wraps on-site (as long as those parties are qualified as per the standard), the operator has the flexibility to appoint the contractors best suited,depending on the specific requirements of a project.
Conclusions
References
1 ISO 24817:2017, ‘Petroleum, Petrochemical and Natural Gas Industries – Composite Repairs for Pipework – Qualification and Design, Installation, testing and Inspection’
2 ASME PCC-2:2018, ‘Repair of Pressure Equipment and Piping’
3 ALEXANDER, Chris, FRANCINI, Bob, ‘State of the Art Assessment of Composite Systems Used to Repair Transmission Pipelines’, Proceeding of IPC 2006
4 www.engineeringtoolbox.com
Bibliography
OHARRIZ, Osmay, ‘Pipelines: The Composite Solutions’, World Pipeline 2016
Yusuke Nishi is a Senior Technical Services Engineer for Belzona Asia Pacific based in Thailand.
Yusuke has been with the company since 2011. He is an experienced professional within the plant maintenance industry specialising in composite repair and protective coatings. He possesses in-depth technical knowledge in various areas of polymeric solutions with a focus on corrosion management and problem solving, gained from over 10 years of experience at Belzona.
